Dr. SaMeH S. Ahmed

Associate Prof. of Environmental Engineering

Ozone cycle overvi


Ozone cycle overview

Three forms (or allotropes) of oxygen are involved in the ozone-oxygen cycleoxygen atoms (O or atomic oxygen), oxygen gas (O2 or diatomic oxygen), and ozone gas (O3 or triatomic oxygen). Ozone is formed in the stratosphere when oxygen molecules photodissociate after absorbing anultraviolet photon whose wavelength is shorter than 240 nm. This converts a single O2 into two atomic oxygen radicals. The atomic oxygen radicals then combine with separate O2 molecules to create two O3 molecules. These ozone molecules absorb UV light between 310 and 200 nm, following which ozone splits into a molecule of O2 and an oxygen atom. The oxygen atom then joins up with an oxygen molecule to regenerate ozone. This is a continuing process which terminates when an oxygen atom "recombines" with an ozone molecule to make two O2molecules.

O + O3 → 2 O2 chemical equation

The overall amount of ozone in the stratosphere is determined by a balance between photochemical production and recombination.

Ozone can be destroyed by a number of free radical catalysts, the most important of which are the hydroxyl radical (OH·), the nitric oxide radical (NO·), the atomic chlorine ion (Cl·) and the atomic bromine ion (Br·). All of these have both natural and man-made sources; at the present time, most of the OH· and NO· in the stratosphere is of natural origin, but human activity has dramatically increased the levels of chlorine and bromine. These elements are found in certain stable organic compounds, especially chlorofluorocarbons (CFCs), which may find their way to thestratosphere without being destroyed in the troposphere due to their low reactivity. Once in the stratosphere, the Cl and Br atoms are liberated from the parent compounds by the action of ultraviolet light, e.g.

CFCl3 + electromagnetic radiation → CFCl2 + Cl

The Cl and Br atoms can then destroy ozone molecules through a variety of catalytic cycles. In the simplest example of such a cycle,[4] a chlorine atom reacts with an ozone molecule, taking an oxygen atom with it (forming ClO) and leaving a normal oxygen molecule. The chlorine monoxide (i.e., the ClO) can react with a second molecule of ozone (i.e., O3) to yield another chlorine atom and two molecules of oxygen. The chemical shorthand for these gas-phase reactions is:

  • Cl + O3 → ClO + O2 – The chlorine atom changes an ozone molecule to ordinary oxygen
  • ClO + O3 → Cl + 2 O2 – The ClO from the previous reaction destroys a second ozone molecule and recreates the original chlorine atom, which can repeat the first reaction and continue to destroy ozone.

The overall effect is a decrease in the amount of ozone, though the rate of these processes can be decreased by the effects of null cycles. More complicated mechanisms have been discovered that lead to ozone destruction in the lower stratosphere as well.

The ozone cycle
Global monthly average total ozone amount.
Lowest value of ozone measured by TOMS each year in the ozone hole.

A single chlorine atom would keep on destroying ozone (thus a catalyst) for up to two years (the time scale for transport back down to the troposphere) were it not for reactions that remove them from this cycle by forming reservoir species such as hydrogen chloride (HCl) and chlorine nitrate (ClONO2). On a per atom basis, bromine is even more efficient than chlorine at destroying ozone, but there is much less bromine in the atmosphere at present. As a result, both chlorine and bromine contribute significantly to the overall ozone depletion. Laboratory studies have shown that fluorine and iodine atoms participate in analogous catalytic cycles. However, in the Earth's stratosphere, fluorine atoms react rapidly with water and methane to form strongly bound HF, while organic molecules which contain iodine react so rapidly in the lower atmosphere that they do not reach the stratosphere in significant quantities. Furthermore, a single chlorine atom is able to react with 100,000 ozone molecules. This fact plus the amount of chlorine released into the atmosphere by chlorofluorocarbons (CFCs) yearly demonstrates how dangerous CFCs are to the environment


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Office hours


Sunday:     12-1

Monday:     12-1

Tuesday:     10-12

Wednesday: 10-11

You are welcome to contact me by at any time

You  may also contact me via WhatsApp group, ..

Ext. 2524

Civil Eng. Students

DON'T miss!


Love your department and be proud of your field of study

As we approaching the second midterm exams..  Get ready and remember our offices are open to answer you . do not hesitate to .contact me if you have difficulties


For CE 370 students : I do apologize for did not attend the extra lab session that proposed to be on Wednesday at 6 am.  Sorry

Good Luck


Announcements


My Dear Students

Please visit the  announcement box for the relevant course and make sure that you can download and upload easily, otherwise

.contact me  to sort it out

There will be an orientation session in the midell of this term to help you select your track in Civil and Environmental Engineering

Event

Special Issue

Electrical Power Resources: Coal versus Renewable Energy



  Published Online on January 2016


Mining Engineering


Mining engineering is an engineering discipline that involves practice, theory, science, technology, and the application of extracting and processing minerals from a naturally occurring environment. Mining engineering also includes processing minerals for additional value.

Environmental Engineering

Environmental engineers are the technical professionals who identify and design solutions for    environmental problems. Environmental engineers provide safe drinking water, treat and properly dispose of wastes, maintain air quality, control water pollution, and remediate sites contaminated due to spills or improper disposal of hazardous substances. They monitor the quality of the air, water, and land. And, they develop new and improved means to protect the environment.

Proverb

Actions speak louder than words

Tawasl

تواصل

College of Eng. MU

http://mu.edu.sa/ar


Univeristies

Universities I've worked in


Assuit University (Home University), Egypt


Imperial College, London, UK


Faculty of Engineering, Al-Mergeb University, Libya


King Saud University, KSA

,Majmaah University


Majmaah University has a very nice web page that provide  all information regarding deanships, colleges, activities,  campuses and many others. Search your request in
http://mu.edu.sa/en

Also visit

My Academic Pages

https://www.researchgate.net/profile/Sameh_Ahemd

and give me


Think


How many red balls we need to make balance 

Sports

Egypt vs Tunisia (Handball final)  30/1/2016


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Course 2016/17-1


  1. Computer Applications in Surveying  CE 473
  2. Surveying 1 CE 370
  3. Photogrammetry CE 474
  4. Surveying II  CE 371
  5. Design I  (round 4) CE 498




The Rules of Life

Rule #7

Latest

Member of the Editorial Board: " Journal of Water Resources and Ocean Sciences"  2013

https://www.researchgate.net/profile/Sameh_Ahmed5/?ev=hdr_xprf

Participating in The Third International Conference on Water, Energy and Environment,(ICWEE) 2015 - American University of Sharjah, UAE 24-26 March 2015 with a Paper and Poster

New article

Recovery of Titania from Waste-Sludge of Majmaah Water Treatment Plant

"Production of Titania Nano-particles from Wast-

Sludge

Coming soon



Results of M2 CE311

Student Conference



Participation  in the 6Th Student Conference

With a paper and oral presentation

From the Senior Design Project CE499 -35

See inside, the paper, and presentation

CE 370 Course

Surveying  I -  CE 370 - 2016-2017-1




Power point


Sheets


Lecture notes


Second Midterm Exam



Results


Model Answer
Inside, please follow:

Student Performance Records

CE 371 Course

Surveying II - CE 371 - 2016-2017-1




Lectures





First midterm exam


Lab


Results

See Inside

Student Performance Records

CE473 Course

Computer Applications in Surveying

CE 473



Lecturers


Power point


Sheets


Exams + Quizzes


Results




CE 474 Course

2015-2016-2 - Photogrammetry  CE474




Available 0-1-2-3-4 Power point

Available

Quizzes 2 and 3 with model Answer

Quizzes
Available Chapter 1,2,3,4,5 Lecture notes

Report 1  Cameras Report

Y

60 marks Exams

See Inside

Student Performance Records


CE 360 Course

Environmental Engineering 1



CE 360: Environmental Engineering 1

37-2

Y PP0-1-2-3,4 Power point
Y 1,2,3,4,5 Chapters

Water quality Poster + Climate Change Reports
will be announced (Quiz #2 will be using D2L- Online Quizzes

Y

Quizzez 2,3 and 4 with model answer and results Exams and results

GE 306 Course

Engineering Report Writing


GE 306: Engineering Report Writing

CE 499 Course

Senior Design 2 - CE 499

Meeting on 14-4-2015

Second Best paper from Senior Design Projects in 2015

Paper title:

Evaluation of Groundwater Quality Parameters using Multivariate Statistics- a case Study of Majmaah, KSA

Students:

Abdullah A. Alzeer

Husam K. Almubark

Maijd M. Almotairi

CE 360-Summer Course

Environmental Engineering I


Welcome to CE360 second Term 2015-2016 

Engineering Practice

 Engineering Practice GE 307

What is your opinion

Contact me

Mobile: 00966598311652

[email protected]

Civil and Environmental Engineering Department
College of Engineering, Majmaah University
Majmaah, P.O. 66, 11952, KSA

Thank you

Your frequent visit to my website has helped  a lot to get the 2nd place in the university competition in the  year 1434-2013... Thanks very mush and please keep following my work

زيارتكم المتكررة لموقعي ساهمت في حصولي على المركز الثاني لاحسن المواقع الشخصية بجامعة المجمعة ...لكم جميعا خالص شكري وتقديري

CE 212 - Summer Course

Properties and Strength of Materials 1

CE 212

Y from PP0 to PP 6 + PDF Power points
Y Midterm #2 + Model Answer + results Exams
Y lab 3 Labs

Solution of Quiz 4 + Results HW


CE 311- Summer Course

Soil Mechanics and Foundation Engineering

CE 311

M2+ model Answer + PP 1-9 = PDF 1-9 all are available

Sheets 2 + 4 with model Answers

Results of M2



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