Dr. SaMeH S. Ahmed

Associate Prof. of Environmental Engineering

Sulfur dioxide


Sulfur dioxide

 



Sulfur dioxide (also sulphur dioxide) is the chemical compound with the formula SO2. It is a poisonous gas with a pungent, irritating smell, that is released by volcanoes and in various industrial processes. Since coal andpetroleum often contain sulfur compounds, their combustion generates sulfur dioxide unless the sulfur compounds are removed before burning the fuel. Further oxidation of SO2, usually in the presence of a catalyst such as NO2, forms H2SO4, and thus acid rain.[2] Sulfur dioxide emissions are also a precursor to particulates in the atmosphere. Both of these impacts are cause for concern over the environmental impact of these fuels


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[edit]Precursor to sulfuric acid

Sulfur dioxide is an intermediate in the production of sulfuric acid, being converted to sulfur trioxide, and then to oleum, which is made into sulfuric acid. Sulfur dioxide for this purpose is made when sulfur combines with oxygen. The method of converting sulfur dioxide to sulfuric acid is called the contact process. Several billion kilograms are produced annually for this purpose.

[edit]As a preservative

Sulfur dioxide is sometimes used as a preservative for dried apricots and other dried fruits owing to its antimicrobial properties, and it is sometimes called E220when used in this way. As a preservative, it maintains the appearance of the fruit and prevents rotting. It is also added to sulfured molasses.

[edit]In winemaking

Sulfur dioxide is an important compound in winemaking, and is designated as parts per million in wine, E number: E220. It is present even in so-called unsulfurated wine at concentrations of up to 10 mg/L.  It serves as an antibiotic and antioxidant, protecting wine from spoilage by bacteria and oxidation. Its antimicrobial action also helps to minimize volatile acidity. Sulfur dioxide is responsible for the words "contains sulfites" found on wine labels.

Sulfur dioxide exists in wine in free and bound forms, and the combination are referred to as total SO2. Binding, for instance to the carbonyl group ofacetaldehyde, varies with the wine in question. The free form exists in equilibrium between molecular SO2 (as a dissolved gas) and bisulfite ion, which is in turn in equilibrium with sulfite ion. These equilibria depend on the pH of the wine. Lower pH shifts the equilibrium towards molecular (gaseous) SO2, which is the active form, while at higher pH more SO2 is found in the inactive sulfite and bisulfite forms. It is the molecular SO2 which is active as an antimicrobial and antioxidant, and this is also the form which may be perceived as a pungent odour at high levels. Wines with total SO2 concentrations below 10 parts per millon (ppm) do not require "contains sulfites" on the label by US and EU laws. The upper limit of total SO2 allowed in wine in the US is 350 ppm; in the EU it is 160 ppm for red wines and 210 ppm for white and rosé wines. In low concentrations SO2 is mostly undetectable in wine, but at free SO2 concentrations over 50 ppm, SO2becomes evident in the nose and taste of wine.]

SO2 is also a very important compound in winery sanitation. Wineries and equipment must be kept clean, and because bleach cannot be used in a winery due the risk of cork taint[citation needed], a mixture of SO2, water, and citric acid is commonly used to clean and sanitize equipment. Compounds of ozone (O3) are now used extensively as cleaning products in wineries due to their efficiency, and because these compounds do not affect the wine or equipment.

[edit]As a reducing agent

Sulfur dioxide is also a good reductant. In the presence of water, sulfur dioxide is able to decolorize substances. Specifically it is a useful reducing bleach forpapers and delicate materials such as clothes. This bleaching effect normally does not last very long. Oxygen in the atmosphere reoxidizes the reduced dyes, restoring the color. In municipal wastewater treatment sulfur dioxide is used to treat chlorinated wastewater prior to release. Sulfur dioxide reduces free and combined chlorine to chloride.]

Sulfur dioxide is fairly soluble in water, and by both IR and Raman spectroscopy, it is known that the hypothetical sulfurous acid, H2SO3, is not present to any extent. However, such solutions do show spectra of the hydrogen sulfite ion, HSO3, by reaction with water and is in fact the actual reducing agent present:

SO2 + H2 HSO3 + H+

[edit]Biochemical and biomedical roles

Sulfur dioxide is toxic in large amounts. It or its conjugate base bisulfite is produced biologically as an intermediate in both sulfate-reducing organisms and in sulfur oxidizing bacteria as well. The role of sulfur dioxide in mammalian biology is not yet well understood. Sulfur dioxide blocks nerve signals from thepulmonary stretch receptors (PSRs) and abolishes the Hering–Breuer inflation reflex.

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